Synthesis of Secondary Amides fromN-Substituted Amidines by Tandem Oxidative Rearrangement and Isocyanate Elimination
نویسندگان
چکیده
منابع مشابه
Catalytic synthesis of amides via aldoximes rearrangement.
Amide bond formation reactions are among the most important transformations in organic chemistry because of the widespread occurrence of amides in pharmaceuticals, natural products and biologically active compounds. The Beckmann rearrangement is a well-known method to generate secondary amides from ketoximes. However, under the acidic conditions commonly employed, aldoximes RHC=NOH rarely rearr...
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ژورنال
عنوان ژورنال: Advanced Synthesis & Catalysis
سال: 2014
ISSN: 1615-4150
DOI: 10.1002/adsc.201400648